No. Napoleon married Josephine in 1796, a marriage validated by a dispensation from the Pope. From that marriage Napoleon never secured any divorce by lawful ecclesiastical authority. He forced a declaration of nullity from some unauthorized clerics, and they put him through a second marriage ceremony in 1810, but this attempted re-marriage was a mockery. The whole thing was a violation of the laws of the Church, and the Church has never acknowledged the second marriage as valid at all.
Radio Replies Volume 1 by Rev. Dr. Leslie Rumble MSC and Rev. Charles Mortimer Carty
